You can login to Multiple Google Talk Accounts Simultaneously with different user name.
First Method
"c:\program files\google\google talk\googletalk.exe" /nomutex
or
Second Method
Open the shortcut properties by right clicking and type "/nomutex" (without quotes)in front of target like this:

Now u can open as many as google talk with different user name
2 Comments:
No doubt d trick is easy nd simple BUT u can also log in with diffrnt accounts on gtalk by opening diffrnt browser windows and logging in by diffrnt gmail user id as gtalk is present in ur gmail inbox browser only.....
*make sure to open diffrnt window and not tab...
i am agree with you anshul but why to open different explorer and signing in them differently if we have this option...
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